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High-intensity ultrasound creates hollow nanospheres and nanocrystals

James E. Kloeppel, Physical Sciences Editor
217-244-1073; kloeppel@illinois.edu

2/22/2005

An SEM of a hollow nanocrystal of molybdenum oxide
Click photo to enlarge
Photo by K.S. Suslick
An SEM of a hollow nanocrystal of molybdenum oxide prepared using high intensity ultrasound to form a layer of amorphous material around a silica nanosphere. The nanosphere is then dissolved away and upon heating the shell crystallizes into a single hollow nanocrystal.

CHAMPAIGN, Ill. — Using high-intensity ultrasound, researchers at the University of Illinois at Urbana-Champaign have created hollow nanospheres and the first hollow nanocrystals. The nanospheres could be used in microelectronics, drug delivery and as catalysts for making environmentally friendly fuels.

“We use high-intensity ultrasound to generate nanoparticles of molybdenum disulfide or molybdenum oxide, which bind to the surface of tiny silica spheres that are much smaller than red blood cells,” said Ken Suslick, the Marvin T. Schmidt Professor of Chemistry at Illinois and a researcher at the Beckman Institute for Advanced Science and Technology. “After heating the spheres to produce uniform coatings, we use hydrofluoric acid to etch away the silica, leaving hollow shells of the desired material.”

Suslick and former postdoctoral research associate Arul Dhas describe their work in a paper that has been accepted for publication in the Journal of the American Chemical Society, and posted on its Web site. Funding was provided by the National Science Foundation.

Ken Suslick behind sonochemistry equipment
Click photo to enlarge
University of Illinois photo
Chemistry professor Ken Suslick and colleagues used high-intensity ultrasound to create hollow nanospheres and the first hollow nanocrystals. The nanospheres could be used in microelectronics, drug delivery and as catalysts for making environmentally friendly fuels.

Hollow nanospheres crafted from molybdenum disulfide could serve as a superior catalyst for removing sulfur-containing compounds from gasoline and other fossil fuels.

“Molybdenum-disulfide is a layered material, but its catalytic activity occurs at its edges,” Suslick said. “By distorting and breaking up the layers, hollow nanospheres offer increased edge-surface area, as well as access to both inner and outer shell surfaces.”

Further processing of hollow spheres made of molybdenum oxide, however, results in the unusual formation of hollow crystals that resemble truncated cubes. Upon heating a second time – referred to as thermal annealing – the hollow molybdenum oxide spheres are transformed into single-crystal boxes with spherical hollow voids.

The sonochemical procedure could be easily applied to other material systems to create additional types of hollow, nanostructured particles, Suslick said.

Sonochemistry arises from acoustic cavitation – the formation, growth and implosion of small gas bubbles in a liquid blasted with sound. The collapse of these bubbles generates intense local heating, forming a hot spot in the cold liquid with a transient temperature of about 9,000 degrees Fahrenheit, the pressure of about 1,000 atmospheres and the duration of about 1 billionth of a second.

For a rough comparison, these values correspond to the temperature of the surface of the sun, the pressure at the bottom of the ocean, and the lifetime of a lightning strike.

Ultrasound consists of sound waves above 18,000 cycles per second, too high-pitched to be audible to human ears.